Abstract
AbstractHard carbons are promising anode materials for lithium, sodium and potassium‐ion batteries attending to their low cost, simple processing technology and outstanding electrochemical performance. However, their complex structure and controversial carrier‐ion storage mechanisms makes difficult the prediction of their performance. Herein, we investigate the insertion storage mechanisms behind of three different alkali metal ions (lithium, sodium and potassium) into a hard carbon composite obtained by the pyrolysis of coffee waste and graphene oxide. The insertion/deinsertion processes have been monitored by galvanostatic intermittent titration technique and operando X‐Ray diffraction. Results reveal that alkaline metal ions follow an adsorption‐intercalation mechanism where the high potential region can be ascribed to the adsorption of the alkaline metal ions on the surface active sites, while slopping region arises from their intercalation between the pseudo‐graphitic micro‐crystallites. Moreover, the graphene‐coffee waste hard carbon exhibits a notorious capacity retention after 300 charge/discharge cycles in all the alkaline metals evaluated.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
