Abstract
AbstractMoO2(acac)2 reacts with water, amides, sulfoxides, and phosphane oxides in aqueous methanol, under mild conditions, to afford a new family of molybdates of composition [Mo2O5L6][Mo6O19] (L = H2O, dimethylformamide, dimethylacetamide, dimethyl sulfoxide, dibutyl sulfoxide, tributylphosphane oxide, triphenylphosphane oxide, hexamethylphosphoramide). The crystal and molecular structures of the two first structurally characterized (μ2‐oxido)bis[dioxidomolybdenum(VI)] hexamolybdates were established by X‐ray diffraction analysis. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)
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