Abstract
Metalation of an ammonium tris(phenol) ligand affords new lithium/sodium derivatives having central pseudocubane motifs in which one of the metallic positions is replaced by a four-coordinate hydrogen atom.
Highlights
Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates†
Metalation of an ammonium tris(phenol) ligand affords new lithium/ sodium derivatives having central pseudocubane motifs in which one of the metallic positions is replaced by a four-coordinate hydrogen atom
Periodic trends in the chemical properties of elements are one of the most important and better established concepts in chemistry.[1]. They are elegantly represented in the Periodic table, which provides a visual representation of the connection between atomic number, electronic structure and group relationships
Summary
Unprecedented participation of a four-coordinate hydrogen atom in the cubane core of lithium and sodium phenolates†. Metalation of an ammonium tris(phenol) ligand affords new lithium/ sodium derivatives having central pseudocubane motifs in which one of the metallic positions is replaced by a four-coordinate hydrogen atom.
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