Abstract

A higher degree of coordination saturation is attainable through the unusual coordination mode in the title compound 1, in which the central pyrazolate groups function both as chelating and as bridging ligands. There is some asymmetry in the bridging, and the N atoms of each μ-η2 :η2 -pyrazolato ligand are 0.07-0.11 Å closer to one of the two Yb centers.

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