Abstract
Two-dimensional laser-induced fluorescence (2D-LIF) spectra are reported for a set of features in the S1 ↔ S0 electronic spectrum of m-fluorotoluene. Two transitions previously assigned to fundamentals are reassigned in the present work. The main reassignments are confirmed with zero-electron-kinetic-energy (ZEKE) spectroscopy. Interactions in the S0, S1 and D0+ electronic states involving vibrational and vibration-torsional (“vibtor”) levels are identified via observed activity. The obtained vibrational wavenumbers compare well to the results of quantum chemical calculations.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
