Abstract
AbstractAn account of our development of reactions to construct N-heterocycles by triggering cyclization–migration tandem reactions from aryl azides, nitroarenes, and aryl amines is described. The reactivity patterns of metal N-aryl nitrenes, nitrosoarenes, N-aryl nitrogen radical anions, and N-aryl nitrenoids are compared.1 Introduction2 Unlocking the Reactivity Embedded in Aryl Azides3 Exploiting the Reactivity of Nitrosoarenes Generated from Nitroarenes4 Radical Anion N-Aryl Nitrogen Reactive Intermediates from Nitroarenes5 Oxidation of Aryl Amines to Access Electrophilic N-Aryl Nitrenoids6 Conclusion
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