Abstract
AbstractSamples of the Ca3Sc2Si3O12 (CSS) host singly doped with Eu2+ or Yb3+, doubly doped with Eu2+ and Yb3+, and triply doped with Ce3+, Eu2+ and Yb3+ were synthesized by a sol–gel combustion process under reducing conditions. Unlike previous reports of Eu2+→Yb3+ energy transfer in other systems, the energy transfer is resonant in the CSS host and the transfer efficiency reaches 100 % for lightly doped samples. The transfer mechanism is multipolar rather than electron transfer for the sample compositions employed herein. The emission intensity of Yb3+ is further enhanced by co‐doping with Ce3+ in addition to Eu2+. The quantum efficiencies of the doped materials range between 9 % and 93 %.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
