Unique and outstanding catalytic behavior of a novel MOF@COF composite as an emerging and powerful catalyst in the preparation of 2,3-dihydroquinazolin-4(1H)-one derivatives.

Abstract

The creation of an emerging porous structure using the hybridization of UiO-66-NH2-MOF, a zirconium-based metal-organic framework (MOF), with a covalent organic framework (COF) based on terephthaldehyde and melamine (UiO-66-NH2-MOF@COF), was assessed using SEM, XRD, EDX/mapping, FT-IR, BET, and TGA analyses. Using the obtained composite as a potential recoverable heterogeneous nanocatalyst, different aldehydes were condensed with isatoic anhydride and anilines or ammonium acetate under solvent-free conditions to create derivatives of 2,3-dihydroquinazolin-4(1H)-one. Examining the catalytic capabilities of the designed UiO-66-NH2-MOF@COF to efficiently produce 2,3-dihydroquinazolin-4(1H)-ones was a standout activity. Low catalyst loading, simple set-up, outstanding yields, and catalyst recoverability are all benefits of this research.