Uniform Plasmonic Response of Colloidal Ag Patchy Particles Prepared by Swinging Oblique Angle Deposition.

Abstract

The plasmonic property of Ag patchy particles fabricated using a colloid monolayer and oblique angle deposition shows significant variations due to the multidomain nature of the monolayer. A swinging oblique angle deposition method is proposed to create uniform patchy particles. Both numerical calculations and experiment show that when the swinging angle is larger than 90°, the resulting plasmonic patchy particles have similar morphology and demonstrate uniform optical response that does not depend on the monolayer domain orientation. These uniform patchy plasmonic particles have great potential for plasmonic-based applications.