Unified solution of the Boltzmann equation for electron and ion velocity distribution functions and transport coefficients in weakly ionized plasmas

Abstract

We present a framework for the solution of Boltzmann's equation in the swarm limit for arbitrary mass ratio, allowing for solutions of electron or ion transport. An arbitrary basis set can be used in the framework, which is achieved by using appropriate quadratures to obtain the required matrix elements. We demonstrate an implementation using Burnett functions and benchmark the calculations using Monte-Carlo simulations. Even though the convergence in transport quantities is always good, the particle distributions did not always converge, highlighting that simple benchmarks can give misleading confidence in a choice of basis. We postulate a different basis, which avoids a spherical harmonic expansion, which is better suited to strong electric fields or sharp features such as low-energy attachment processes.