Abstract

AbstractThe influence of uniaxial stress on the vibrational mode of the Cu–H complex at 3192 cm–1 in ZnO is studied. It is shown that the split patterns are consistent with the stretching mode of a bond‐centered hydrogen located in the basal plane between substitutional Cu and O. Quantitative analysis of the stress effects reveals two low energy modes with frequencies of 25 and 49 cm–1. Upon substituting deuterium for hydrogen they shift to 22 and 36 cm–1, respectively. The origin of the low energy modes is discussed. (© 2006 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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