Abstract
A new aromatic ladder polymer with a polyacene skeleton shows an unexpectedly high flexibility of its double-stranded backbone.
Highlights
In this report we describe the synthesis of the new graphene nanoribbons (GNRs)-type ladder polymer PAL comprising a polyacene skeleton together with an in-depth analysis of its optical properties, especially by time-resolved photoluminescence (PL) spectroscopy and PL investigations on the single-chain level
The results were further compared to the properties of the wellstudied methyl-substituted poly(para-phenylene), MeLPPP, as prototypical rigid-rod conjugated ladder polymer.[12,20]
This study reports synthesis and photophysical characterization of a new ladder polymer PAL (P2) comprising a polyacene skeleton, with the optical properties set in comparison to the extensively studied MeLPPP ladder polymer
Summary
In this report we describe the synthesis of the new GNR-type ladder polymer PAL comprising a polyacene skeleton together with an in-depth analysis of its optical properties, especially by time-resolved photoluminescence (PL) spectroscopy and PL investigations on the single-chain level. Time-resolved PL experiments were conducted for MeLPPP and PAL polymers in solvents of different viscosity, as a function of temperature.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.