Abstract
Water in our environment is ever present, particularly in our atmosphere, from which it may be adsorbed by materials hygroscopically. At the molecular level, the binding of water molecules to various materials is driven by weak interactions but can have profound effects on physical properties, including the donor-acceptor interactions in charge transfer (CT) salts. Herein we present the unexpected three-state hydrochromatic switching of a bipyridinium-based donor-acceptor self-complex with changes in relative humidity (RH) and subsequent stable hydrate formation. RH is typically an overlooked variable that can vary greatly. These findings suggest that care should be taken to consider fluctuations in RH when characterizing the solid state optical band gap and CT absorption bands for organic donor-acceptor CT salt complexes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
