Abstract
This work revisits the temperature dependence of 1H paramagnetic shift in nickelocene as a potential nuclear magnetic resonance (NMR) thermometer under fast magic angle spinning (MAS) rate. Surprisingly, an abnormal temperature dependence of 1H paramagnetic shift has been observed. In addition to a 1/T dependence term, a 1/T2 dependence term must be included to correctly describe the curvature behavior of the δ1H-T correlation under fast MAS rate.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
