Abstract

2- [1-(Bromoacetoxy)ethoxy]ethyl isothiocyanate (II) (BrCH2CO2CH(CH3)OCH2CH2. N-C-S) was found to be an adduct of 2-vinyloxyethyl isothiocyanate (I) with bromoacetic acid. Upon storage, (II) rearranges to previously unreported 1-bromo-3-aza-4-oxo-5-thiaheptanoic acid (III) (BrCH2CH2NHC(O)CH2C02H).

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