Abstract
The degree of crystallinity, morphology and electrochemical properties of a nanocomposite formed by stabilized alpha-Ni(OH)2 nanoparticles and bentonite nanoflakes is strongly influenced by the vacuum drying process, either at room temperature or by freeze-drying (lyophilization). Alpha-Ni(OH)2 nanoparticles induced the formation of intercalation nanocomposites exhibiting higher structural organization than in the precursor clay. Also, lyophilization process preserved the structure of the nanocomposites in aqueous suspension and/or induced the disaggregation of nanoflakes, producing materials with lower degree of crystallinity, larger interlamellar distances and electrochemically more active than those obtained by conventional vacuum drying. In fact, the lyophilized materials exhibited more than twice as large density of current for electrocatalytic oxidation of methanol (37 against 14 mA cm−2) indicating its potentiality for development of sensors and fuel cells.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.