Abstract
Tire cord steel is widely used in the tire production process of the vehicle manufacturing industry due to its excellent strength and toughness. Titanium nitride (TiN) inclusion, existing in tire rod, has a seriously detrimental effect on the fatigue and drawing performances of the tire steel. In order to control its amount and morphology, the precipitation behavior of TiN during solidification in SWRH 92A tire cord steel was analyzed by selected thermodynamic models. The calculated results showed that TiN cannot precipitate in the liquid phase region regardless of the selected models. However, the precipitation of TiN in the mushy zone would occur at the final stage during the solidification process (at solid fractions greater than 0.98) if the LRSM (Lever-rule model was applied for the N and Scheil model for Ti) or Ohnaka models (without considering the effect of carbon on secondary dendrite arm spacing (SDAS)) were adopted. For the Ohnaka model, in the case when the effect of carbon on SDAS was considered, TiN would probably precipitate in the solid phase zone rather than precipitate in the liquid phase region or mushy zone.
Highlights
Tire cord steel is a kind of high-carbon steel and possesses high strength and toughness.it is widely used in the production of tires for cars and airplanes [1]
Jiang et al [4] found that the solidification segregation ratio of Ti was far greater than that of N, and reported that Titanium nitride (TiN) inclusion would not precipitate until the solid fraction reached 0.9 when using SWRH 82A tire cord steel
Can be deduced, which is almost the same as the theoretical solidus temperature (TS = 1636 K) of the studied tire cord steel. This result suggests that TiN will not precipitate in the mushy zone until nearly close to complete solidification
Summary
Tire cord steel is a kind of high-carbon steel and possesses high strength and toughness. Non-metallic inclusions, such as oxide-or Ti-bearing inclusions, existing in tire cord steel have serious detrimental effects on the drawing performance and fatigue properties. TiCx N1-x ), a continuous solid solution formed via replacing partial moles of N in TiN crystal with C has similar properties to those of TiN It has a detrimental effect on the fatigue performance and, as a result, leads to wire breaking during the drawing and stranding processes [7]. Jiang et al [4] found that the solidification segregation ratio of Ti was far greater than that of N, and reported that TiN inclusion would not precipitate until the solid fraction reached 0.9 when using SWRH 82A tire cord steel. In order to make the mechanism of TiN precipitation clearer, a series of relevant studies were initiated in this paper, to show guidance for the development of ultra-high strength grade steels
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