Understanding the role of gravity in the crystallization suppression of ZBLAN glass

Abstract

ZBLAN (ZrF4–BaF2–LaF3–AlF3–NaF) glass fibers are excellent materials for the use in many applications, such as fiber optics, fiber amplifiers, and lasers for cutting, drilling, and surgery. The main advantage of ZBLAN glasses over other glasses, such as silica, is its superior infrared transmissibility. The theoretical optical transmission spectrum for a ZBLAN fiber is from 0.3 μm in the UV to 7 μm in the IR region. The main obstacle with ZBLAN glass is the extrinsic losses from impurities, which includes crystallites formed during the manufacturing process. Due to ZBLAN’s narrow working range, crystallites easily form during the drawing process, which inhibits the materials transmissibility. Microgravity (μ-g) processing has been proven to suppress crystallization in ZBLAN glass, thus allowing the material to reach its theoretical loss coefficient. Past researchers have shown that this phenomenon exists, but the mechanism of crystallization suppression in a microgravity environment is not well understood. This research endeavors to understand the role that gravity plays on the crystallization suppression of ZBLAN glass. The outcome of this study will impact the production of superior mid-IR fiber optics and could lead to a more feasible manufacturing technique. The main conclusion developed from this study is that the process is heavily dependent upon mass transfer kinetics such as diffusion and buoyancy-driven convection. Thus, suppressing buoyancy-driven convection, at relevant drawing temperatures, suppresses crystallization growth in ZBLAN glass. This theory was proven through microgravity experimentation, analytical, and computational modeling.