Abstract
The core–shell structure of Ti/Nb precipitates in UNS S44660 was revealed by focused ion beam–transmission electron microscopy (FIB–TEM). In the bromide solution, the Nb in the shell is preferentially and selectively eluted, leaving a micro-crevice. The combined effect of the strong anodic adsorption of Br− and the large strain field in the shell promotes the free dissolution of residual Mo. Micro-crevices surround the Ti-rich nucleus and expand into pits. Consequently, pitting preferentially initiates at the Ti/Nb precipitates, which was verified by scratching electrode tests and immersion tests in bromide solutions.
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