Understanding the effects of operating conditions on the water management in anion exchange membrane fuel cells

Abstract

While water management in Anion Exchange Membrane Fuel Cells (AEMFCs) is seen as crucial for performance and durability, measurements of water management within operating cells remain few. In this work, we measured the performance of an H2/O2 AEMFC based on a low-density polyethylene membrane AEM, PtRu/C anode and Fe–N–C cathode for various combinations of inlet relative humidities, gas pressures and flow rates. Simultaneously, the anode and cathode outlet relative humidities were measured using humidity sensors, from which the amount of water removed from the cell could be quantified for each side. The data shows that back-diffusion of water from anode to cathode results in increasing outlet relative humidity with increased current density, both at anode and cathode. Water produced in the AEMFC was thus removed from both sides. The maximum current density was found to be strongly connected to anode flooding, which is also the main cause for hysteresis during potentiodynamic scans. However, under atypical operating conditions, the cell performance may also be limited by low humidity at the cathode, with associated low ionomer conductivity. Overall, it is concluded that water management of AEMFC with thin AEMs can be achieved by playing with both the anode and cathode operating conditions.