Unconventional Synthesis of Metal (Ni, Co, Ag) Antimony Alloy Particles.

Abstract

Bimetallic alloy materials attract interest owing to their properties and stability compared to pure metals, especially alloys with nanoscale dimensions. Metal antimony (MSb) alloys, specifically NiSb, are widely used for charge storage applications due to their high stability. Most synthetic approaches to form these materials require drastic conditions (e.g., high temperatures, potent reducing agents, and extended reaction times), limiting control over the final morphology. The other viable approach is a galvanic replacement that uses unstable materials as precursors. In this work, we present a new and facile method to prepare several MSb (M = Ni, Co, Ag) alloys with shape control by reacting Sb2S3 particles with a metal(M)-sulfide single source precursor in trioctylphosphine (TOP) under mild conditions. Furthermore, we explore the role of TOP as a reducing agent and demonstrate how both alloy constituents are crucial for mutual stabilization. Electrochemical studies are also performed on these NiSb particles, showing their ambipolar nature and allowing their utilization as the active ingredient in the demonstrated high-energy-density symmetric supercapacitor.