Abstract
Formyl-TMM (Iron)tricarbonyl 3 reacts with a high diastereoselectivity with organozinc derivatives to Iron stabilized TMM-alcohols. These are decomplexed, under partial hydrogenation, by photolysis in acetic acid to give allylic and homoallylic isoprenoic alcohols. Starting from the optically active complex (+)- 3, this allows a rapid synthesis of (R)-(-)-Ipsdienol of high ee.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
