Ultraviolet-induced degradation of Ziegler-Natta and metallocene catalyzed polyethylenes

Abstract

The metallocene revolution has aroused a storm of interest and associated questions regarding the performance and durability of polyolefins. This new technology has impacted the additives used to stabilize and process polymers. In this work, Ziegler-Natta and metallocene polyethylene (PE) samples were exposed to natural weather conditions under high doses of ultraviolet radiation, high temperature, and increased humidity. Weather-induced degradation of the two sets of PEs was studied using gel permeation chromatography, mechanical properties testing, differential scanning calorimetry, and Fourier transform infrared spectroscopy. The gel permeation chromatography analysis indicated the change in molecular weight distribution and molecular weights of metallocene PE to be more stable than conventional Ziegler-Natta PE. The tensile properties of metallocene PE are known to have higher values than Ziegler-Natta PE. The former exhibited a lower drop rate in mechanical properties when exposed to natural weather. Formations of nonvolatile carbonyl oxidation products, which absorb in the infrared region with a maximum absorbance level at 1742 cm−1 were determined. This indicated a higher rate of photo-oxidative and thermal degradation of Ziegler-Natta PE as compared with metallocene PE. The ultraviolet stabilization of metallocene PE may require different doses and a new kind of stabilizer system that can impart a longer useful lifetime and are cost effective for PE used for outdoor purposes. © 2000 John Wiley & Sons, Inc. J Appl Polym Sci 78: 1591–1596, 2000