Ultrathin Water Layer Conservation by "Nano-forest" in a Three-Dimensional Interface Regulates Energy Flow to Boost Solar Evaporation.

Abstract

Solar-driven interfacial evaporation technology utilizes materials to form a thin layer on the water's surface, absorbs sunlight on this layer, completes the light-to-heat conversion, heats up the water, and vaporizes it. This greatly reduces energy loss to bulk water and greatly improves the evaporation rate for producing clean water. Additionally, three-dimensional (3D) evaporators are increasingly being applied in this field, and the cold surface generated by the rapid evaporation in the 3D evaporator can utilize environmental heat to achieve a net energy gain for the system. Both strategies improve the evaporation rate of the system, but 3D materials typically have high water contents and cannot avoid energy flow into non-evaporated water. To address this, we introduce the advantages of interfacial evaporation into 3D evaporation by constructing an evaporator with a highly conductive copper core skeleton and an outer layer of ultrathin water and by reasonably constructing interconnected evaporation frameworks. Investigating and optimizing the mutual influence of the ultrathin water layer on the framework, an evaporator with 40 pores per inch (ppi) can reach a maximum of 24.4 kg·m-2 h-1, indicating that 3D interfacial evaporators with ultrathin water layers concentrate energy flow to stimulate high evaporation rates. This strategy will promote the development of photothermal evaporation technology.