Abstract

HighlightsThe capacity fading mechanism of the conventional Na3V2(PO4)3//Na3V2(PO4)3 (NVP//NVP) cell has been investigated.All-solid-state ferroelectric-engineered composite electrolyte could improve the electrolyte–electrode interfacial stability as well as the interfacial ion conduction of the Na-ion battery using the NVP anode.Outstanding cyclic stability has been achieved in the all-solid-state Na-ion battery using the NVP anode, with a capacity fading rate as low as 0.005% per cycle.

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