Abstract
The use of a new technical method to introduce perfluoroalkyl groups on a desired position of molecules is a challenge for fluorine chemistry. Ultrasound provides a potential solution to this problem. We have found that it is now possible to introduce a perfluoroalkyl group to carbon-oxygen and carbon-carbon double bonds, and to carbon-carbon and carbon-nitrogen triple bonds with perfluoroalkyl iodides by the use of ultrasonically dispersed zinc. Regio- and stereochemical information is discussed. ▪
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