Ultrasound-assisted acid/enzymatic hydrolysis preparation of loquat kernel porous starch: A carrier with efficient palladium loading capacity

Abstract

Porous starch, with excellent renewal and thermodynamic stability characteristics, could be utilized as a novel carrier for metals. In this research, starch was obtained from wasted loquat kernel (LKS) and converted into loquat kernel porous starch (LKPS) through ultrasound-assisted acid/enzymatic hydrolysis. Then, LKS and LKPS were utilized for loading with palladium. The porous structures of LKPS were evaluated by the results of water/oil absorption rate and N2 adsorption analysis, and the physicochemical properties of LKPS and starch@Pd were analyzed by FT–IR, XRD, SEM–EDS, ICP–OES, and DSC–TAG. LKPS prepared by the synergistic method formed a better porous structure. Its specific surface area was 2.65 times that of LKS, and the water/oil absorption capabilities were considerably improved to 152.28 % and 129.59 %, respectively. XRD patterns showed that the presence of diffraction peaks at 39.7° and 47.1°, indicating successful palladium loading onto LKPS. The EDS and ICP–OES results revealed that the palladium loading capacity of LKPS was superior to that of LKS, with a significantly increased loading ratio of 2.08 %. In addition, LKPS@Pd exhibited excellent thermal stability, with a temperature range of 310–320 °C. Therefore, LKPS was a palladium carrier with highly efficient loading ratio, and LKPS@Pd had promising properties as a competent catalyst.