Abstract

Using the phase-time approach, the dependences of the speed of sound on the temperature and composition are measured in CsCl–CsBr, CsCl–CsI, and CsBr–CsI molten binary mixtures. The adiabatic compressibility of these mixtures is calculated from the experimental values of speed and density. Negative deviations from the additive values of the speed of sound and positive deviations from the additive values of adiabatic compressibility are observed. The magnitude of deviation depends on the ratio of the sizes of anions in the mixtures.

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