Abstract

Many organic crystals with orthorhombic symmetry exhibit electro-optic, ferroelectric, and triboluminescence properties. The potassium salt of phthalic acid (KAP), with the formula C8H5O4K, finds application in soft x-ray spectroscopy due to its large d spacing and has been reported to be piezoelectric as well. KAP crystallizes into orthorhombic structure with space group Pca21 All nine elastic constants of KAP have been determined by measuring the velocity of longitudinal and transverse ultrasonic waves propagating along different symmetry directions. Velocities have been measured by the ultrasonic pulse echo overlap technique by injecting waves generated by quartz transducers through a suitable bonding medium into the crystal. The McSkimin Δt correction has been applied to determine the velocities accurately. The temperature variation of selected elastic constants over the range 300–420 K has also been measured and reported.

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