“Ultralow” sliding wear polytetrafluoro ethylene nanocomposites with functionalized graphene

Abstract

The dry friction and sliding wear behavior of sintered polytetrafluoro ethylene containing various amounts of functionalized graphene were studied in this work. Graphene was incorporated in 0, 0.25, 0.75, 1, 2 and 4 vol.%, respectively. Sliding wear tests were performed in ring(metal)-on-plate(polytetrafluoro ethylene) test rig under ambient temperature setting 1 m/s sliding speed and 1 MPa contact pressure. The dynamic coefficient of friction and specific wear rate (ws) data were determined. Very low coefficient of frictions (0.12–0.14) were measured for polytetrafluoro ethylene containing 2 or 4 vol.% graphene, which was attributed to the formation of a tribofilm on the countersurface. Specific wear rate went through a maximum (peaked at doubling that of the unmodified polytetrafluoro ethylene at about 0.75 vol.% graphene) as a function of graphene content. Ultralow wear rate data in the range of 10−6 mm3/(N.m) were measured for the polytetrafluoro ethylene nanocomposites with 2 and 4 vol.% graphene. This was reasoned by the formation of a robust tribofilm, the development of which was followed by scanning electron microscopy by inspecting the worn surface of polytetrafluoro ethylene nanocomposites and that of the steel ring of the ring(metal)-on-plate(polytetrafluoro ethylene) test rig. Fourier transform infrared spectroscopic results confirmed the formation of carboxyl groups in the tribofilm. They were supposed to react with the functional groups of graphene and to create complexes with the metal countersurface ensuring the tribofilm with high adhesion and cohesion strengths.