Ultralong-range triatomic Rydberg molecules in an electric field

Abstract

We investigate the electronic structure of a triatomic Rydberg molecule formed by a Rydberg atom and two neutral ground-state atoms. Taking into account the s-wave and p-wave interactions, we perform electronic structure calculations and analyze the adiabatic electronic potentials evolving from the Rb Rydberg degenerate manifold. We hereby focus on three different classes of geometries of the Rydberg molecules, including symmetric, asymmetric and planar configurations. The metamorphosis of these potential energy surfaces in the presence of an external electric field is explored.