Ultralight, superhydrophobic and fire-resistant nitrogen-doped graphene aerogel for oil/water separation

Abstract

The simultaneous achievement of graphene aerogels with low density, high adsorption capacity and selectivity, as well as high mechanical strength, holds great significance but remains a challenging task. By adjusting the concentration and ratio of graphene oxide, dopamine and L-ascorbic acid, the hydrogel without obvious volume shrinkage and stability was synthesized by hydrothermal reaction at low temperature, after freeze-drying and calcination, nitrogen doped graphene aerogel (NGA) with ultralight, superhydrophobic, superoleophilic, fire-resistant, and compressible/recoverable were obtained. The density of NGA is only about 1.9 mg/cm3, and the water and oil contact angles in air are 153.3° and 0°, respectively. Given the aforementioned beneficial features, NGA can efficiently select and adsorb multifarious of oils and organic solvents in oil/water mixtures so as to achieve oil/water separation. Remarkably, NGA exhibits an impressive adsorption capacity of up to 150–305 times its own weight, and it also possesses excellent adsorption recyclability. Therefore, NGA has great potential in the treatment of oil pollution in the water environment.