Abstract

A novel deep-blue emissive dopant material, 2,7-bis(9,9-dimethylacridine-10(9H)-yl)-9,9-diphenyl-9H-thioxanthene 10-,10-dioxide (DMA-ThX), is synthesized for use in highly-efficient thermally activated delayed fluorescence organic light-emitting devices (TADF OLEDs). The molecular design of DMA-ThX retains the overlap between the lowest singlet excited state (S1) and the lowest triplet excited state (T1) because of its twisted molecular structure. From photoluminescence emission measurements at low temperature, the difference between the S1 and the T1 energy levels of DMA-ThX is found to be 0.07 eV. Furthermore, the external quantum efficiency of the deep-blue-emitting TADF OLEDs with DMA-ThX-doped bis[2-(diphenylphosphino)phenyl] ether oxide is 18.4%, which is significant, and the Commission Internationale de l'Eclairage coordinates are (0.14, 0.14), indicative of very pure deep-blue emission.

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