Abstract
AbstractHere, we develop a facile synthesis route to fabricate ultrafine palladium nanoparticles embedded in N‐doped porous carbon material (Pd@N‐PCM), in which carbazole‐covalent triazine polymers obtained by Friedel‐Crafts alkylation at room temperature are used as precursor of N‐doped carbon. The obtained Pd@N‐PCM as a green catalyst shows the high catalytic efficiency (TOF=982 h−1) for Suzuki‐Miyaura coupling reaction of chlorobenzene under the mild reaction condition (room temperature, a non‐toxic solvent and air atmosphere). The brilliant catalytic activity of Pd@N‐PCM gives the credit to the concerted effect from the ultrafine Pd and N‐doped porous carbon.
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