Ultrafine Mo-Doped Co2P Nanorods Anchored on Reduced Graphene Oxide as Efficient Electrocatalyst for the Hydrogen Evolution Reaction**Supported by the National Natural Science Foundation of China (Grant Nos. 11874027, 11774124, and 11504126) and the China Postdoctoral Science Foundation (Grant Nos. 2019T120233 and 2017M621198).

Abstract

One-dimensional (1D) transition metal phosphides (TMPs) with large specific surface areas, high charge transfer efficiency and excellent electrical conductivity have attracted significant attention in hydrogen evolution reaction (HER) as versatile and active catalysts. Herein, the sub-4 nm Mo-Co2P ultrafine nanorods (NRs) anchored on reduced graphene oxide (rGO) were successfully synthesized by a colloidal mesostructured strategy. Electrochemical test results reveal that the Mo-Co2P@rGO electrode exhibits superior activity with overpotentials of 204 mV and Tafel slope of 88 mV/dec for HER at 10 mA/cm2, relative to the Co2P@rGO electrode in 0.5 M H2SO4 solution. This improvement could be ascribed to the Mo doping, which results in more active sites, higher electrical conductivity and faster electron-transfer rates. This versatile strategy will provide a promising pathway for transition metal-doped compounds as an efficient catalyst.