Abstract
AbstractUltrafine copper nanopalm tree‐like frameworks conformally decorated with iron oxide (Cu NPF@Fe2O3) are prepared by a facile electrodeposition method utilizing bromine ions as unique anisotropic growth catalysts. The formation mechanism and control over Cu growth are comprehensively investigated under various conditions to provide a guideline for fabricating a Cu nanoarchitecture via electrochemical methods. The optimized Cu NPFs exhibit ultrathin (<90 nm) and elongated (2–50 µm) branches with well‐interconnected and entangled features, which result in highly desirable attributes such as a large specific surface area (≈6.97 m2 g−1), free transfer pathway for Li+, and high electrical conductivity. The structural advantages of Cu NPF@Fe2O3 enhance the electrochemical kinetics, providing large reactivity, fast Li+/electron transfer, and structural stability during cycling, that lead to superior electrochemical Li storage performance. The resulting Cu NPF@Fe2O3 demonstrates a high specific capacity (919.5 mAh g–1 at 0.1 C), long‐term stability (801.1 mAh g–1 at 2 C, ≈120% retention after 500 cycles), and outstanding rate capability (630 mAh g–1 at 10 C).
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