Abstract
In this Letter, we report measurements of the picosecond relaxation time of trans-stilbene in S1 under collisionless conditions. By acurate determination of the zero-time in our picosecond pump-probe experiments we obtained r = 3 ± 0.5 ps, which is entirely consistent with our earlier measurements of IVR rates of stilbene in bulbs and beams. This establishes the molecular nature of the decay in these picosecond pump-probe multiphoton ionization (or mass spectrometry) experiments.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
