Ultrafast dyeing wastewater purification by high-performance and reusable lignin-derived activated porous carbon filter

Abstract

Achieving ultrafast purification during filtration while maintaining high adsorption capacity and low-cost filter production is a critical challenge that must be addressed immediately to promote large-scale water filter applications, particularly in remote areas without wastewater purification plants. Herein, low-cost, renewable lignin was used as a carbon source precursor to produce a high-performance, reusable activated porous carbon filter for ultrafast dye wastewater purification. Lignin-derived active porous carbon (LAPC) can achieve a high specific surface area (2276 m2/g) by using a lower amount of KOH (a mass ratio of 0.4 KOH to precursor) during the activation process, which not only meets the requirements of water transport and dye adsorption, but also reduces manufacturing costs. Owing to the pore-filling effect and electrostatic interaction, the LAPC particles displayed a high removal capacity of 1800 mg/g in the static adsorption, higher than most of the reported porous carbon. Furthermore, LAPC filters assembled from a flow of LAPC particles achieve significant dye removal (99.82 % in 30 s) during the dynamic adsorption process. Both anionic and cationic dyes can be removed and clean water can be produced simultaneously by simple dynamic filtration. Moreover, the LAPC filter could be reused for wastewater purification with a high removal efficiency (more than 95 % after 7 cycles of regeneration and use). This continuous operation, strong absorption versatility, and high efficiency of LAPC filter device for complex hybrid dyes system make it have a bright prospect in industrial dyeing wastewater treatment fields.