UiO series of metal-organic frameworks composites as advanced sorbents for the removal of heavy metal ions: Synthesis, applications and adsorption mechanism

Abstract

Heavy metal pollution has threatened the ecological environment and human health, therefore, effective removal of these toxic pollutants from various complex substrates is of great significance. So far, adsorption is still one of the most effective approaches. Metal-organic frameworks (MOFs), which are porous crystalline materials consisting of metal ions or metal clusters and organic ligands through coordination bonds. Due to their high surface area, porosity, as well as good chemical/thermal stability, the materials have recently attracted great attention in environmental analytical chemistry. This review mainly focused on the recent studies about the applications of UiO series MOFs and their composites as the emerging MOFs, which have been used effectively for the adsorption and removal of diverse heavy metal ions from a variety of environmental samples as novel adsorption materials. Moreover, an elaboration about UiO-MOFs and its composites including the synthetic methods and the applications of these materials in the removal of heavy metal ions were presented in detail. In addition, the adsorption characteristics and mechanism of UiO-MOFs as solid sorbents for heavy metal ions were discussed, including adsorption isotherms equation, adsorption thermodynamics, and kinetics. To this end, the developing trends of MOF-based composites for the removal of heavy metal ions had also prospected. This review will provide a new idea for the study of the adsorption mechanism of heavy metal ions on sorbents and the development of high-performance media for the efficient removal of pollutants in wastewater.