Abstract

The results of a laser ablation inductively coupled plasma mass spectrometry (LA-ICP-MS) U–Pb dating and a Hf isotope study of zircon crystals separated from small eclogite xenoliths found in Devonian kimberlites within the Prypyat horst, Ukraine, have been reported. The studied area is located in the junction zone between the Sarmatian and Fennoscandian segments of the East European Platform. Four laser ablation sites on two zircon grains yielded Paleoproterozoic U–Pb ages between 1954 ± 24 and 1735 ± 54 Ma. In contrast, three of four Hf sites revealed negative εHf values and Paleoarchean to Mesoarchean model ages, excluding the possibility that the eclogite xenoliths represented segments of a juvenile Paleoproterozoic subducted slab or younger mafic melts crystallized in the subcontinental lithospheric mantle. A single laser ablation Hf spot yielded a positive εHf value (+3) and a Paleoproterozoic model age. Two models for eclogite origin can be proposed. The first foresees the extension of the Archean lower-crustal or lithospheric roots beneath the Sarmatia–Fennoscandia junction zone for over 200 km from the nearest known outcrop of Archean rocks in the Ukrainian Shield. The second model is that the Central Belarus Suture Zone represents a rifted-out fragment of the Kola–Karelian craton that was accreted to Sarmatia before the actual collision of these two segments of Baltica.

Highlights

  • Eclogites having MORB-like geochemistry are often considered as an evidence of subduction [2,3,4,5,6,7], and some have been used to suggest the operation of global plate tectonics since the Paleoproterozoic [4,5,8,9,10]

  • We reported results of U–Pb dating and Hf isotope studies of two rare zircon crystals that were extracted from small eclogite xenoliths

  • Zircons from two eclogite xenoliths in Devonian kimberlites had U–Pb ages in the range of 1955 to 1735 Ma (207 Pb/206 Pb ages), which corresponded to the ages of the rock assemblage constituting the Central Belarusian Suture Zone

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Summary

Introduction

Eclogite is a metamorphic rock of basic (basaltic) composition predominantly made of garnet and Na-bearing clinopyroxene (omphacite) that is rare at the Earth surface. It indicates high-pressure (over 1.2 GPa) and relatively high-temperature (over 500 ◦ C) conditions of metamorphic crystallization [1], which may be achieved either in the upper mantle or in the lowermost part of a thickened crust. The eclogite mineral assemblage crystallizes due to the metamorphism of mafic rocks comprising the subducting plate. Retrogressed eclogites from Paleoproterozoic orogens interpreted as mafic rocks metamorphosed at high pressure in a thickened crust were discussed by [5]

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