Abstract

Magnetic and electric dipole two-photon absorption (MED-TPA), recently introduced as a spectroscopic technique for studying transitions between states of opposite parities, is investigated from a theoretical point of view. An approximation referred to as weak quasiclosure approximation is used together with symmetry adaptation techniques to calculate the transition amplitude between states having well-defined symmetry properties. Selection rules for MED-TPA are derived and compared to selection rules for parity-forbidden electric dipole two-photon absorption.

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