Abstract
A new technique of alternate two-wavelength oscillation of a CO2 laser is discussed for application to various differential absorption spectroscopic measurements. Power-balanced, two-adjacent branch oscillation using a single CO2 laser was achieved by modulating the angle of a mirror inside the laser cavity and adjusting automatically the cavity length. The two-wavelength modulation frequency was extended up to about 1.2 kHz. Line tuning and power modulation characteristics were studied. The laser was used in long-path differential absorption measurements of ethylene air pollution molecules to demonstrate the capability of this power-balanced, two-wavelength oscillation method. The minimum detectable absorption was nearly 1×10−3 in a short-path cell experiment and 3×10−3 in a long-path experiment.
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