Abstract
Two transition metal coordination polymers (CPs), namely, Cd(1,4-NDC)(py) (1), Co2(1,4-NDC)2(DMF)2 (2) (1,4-NDCH2=1,4-naphthalenedicarboxylic acid, py=pyridine, DMF=N,N-dimethylformamide) have been synthesized and characterized. Compound 1 contains one-dimensional chains, which are further linked by the NDC2− ligands to form a three-dimensional framework with a 5,5T2 topology network. There exist two types of left-hand helical chains interconnected to each other through the Cd(II) center in compound 1. Although compound 2 has been reported previously, in this work the synthetic method of 2 is modified to obtain high quality crystals. In addition, the magnetic property of compound 2 is investigated, which shows the metamagnetic behavior induced by the external field.
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