Abstract
The two-step mechanochemical preparation of carbene-pyridine complexes of palladium and platinum is reported. The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHC-containing compounds.
Highlights
The two-step mechanochemical preparation of carbene–pyridine complexes of palladium and platinum is reported
The organometallic products, which represent a class of commercially available catalysts, are rapidly formed in excellent yield proving solvent-free synthesis to be a viable synthetic alternative even in the case of NHCcontaining compounds
Solid state synthesis of organometallic adducts dates back almost 50 years,[3] little progress has been made in this field since
Summary
The two-step mechanochemical preparation of carbene–pyridine complexes of palladium and platinum is reported. Our group has previously reported solid-state syntheses of transition-metal coordination complexes in which target species can be formed rapidly and quantitatively by grinding together appropriate starting materials.
Sign-in/Register to view highlights & summary Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
