Two quasi-spherical molecules [1,4-diazabicyclo(3.2.2)nonane]X (X = ClO4, ReO4) exhibit switchable phase transition, dielectric and second-harmonic-generation properties

Abstract

Two quasi-spherical molecules [3.2.2-Hdabc]X (1,4-diazabicyclo[3.2.2]nonane = 3.2.2-dabcn, X = ClO4, ReO4) with a high phase transition temperature exhibited switchable phase transition as well as dielectric and SHG properties.