Two-Pronged Approach: Synergistic Tuning of the Surface and Carbon Core to Achieve Yellow Emission in Lignin-Based Carbon Dots.

Abstract

In this study, yellow emissive lignin-based carbon dots (Y-CDs) were successfully prepared through a synergistic approach to adjust its surface and carbon core states. The lignin was initially effectively oxidized and carboxymethylated to impart abundant -COOH onto the precursor, which eventually adjusts the surface state of the CDs. Subsequently, α-naphthol was employed during the solvothermal treatment of lignin with the aim of elevating the sp2 domain content in the CDs and, thus, adjusting its carbon core state. The obtained Y-CDs possessed abundant carboxyl groups and nanoscale spherical shape with an average diameter of 5.21 nm. Meanwhile, the energy gap of Y-CDs was 2.46 eV and the optimal emission wavelength was 561 nm under the excitation wavelength of 410 nm. Synergistic adjusting carbon core and surface of the Y-CDs would alter the surface charge distribution and promote the delocalization of π electrons, and thus lead to a red shifting with the emission wavelength of 154 nm. Furthermore, a shape memory film with excellent recovery performance and fluorescent properties was designed by embedding the Y-CDs into polyvinyl alcohol (PVA) polymer. The incorporation of Y-CDs could impart the film with considerable high-value applications in the fields of intelligent sensing, biomedicine, and tissue engineering.