Abstract
A two-pot synthesis of unsymmetrical hetero[7]helicenes from commercially available substrates has been established. Combining the acid-mediated annulation with the electrochemical domino reaction (oxidative hetero-coupling/dehydrative cyclization sequence) in a single protocol afforded oxaza[7]helicenes with up to 45% overall yield. The photophysical properties of these [7]helicenes have been studied, and their absorption and fluorescence patterns were explained by DFT calculations.
Full Text 
Sign-in/Register to access full text options
Sign-in/Register to access full text options 
Published version (
Free)
Free) 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call
