Abstract
Two new inorganic–organic hybrid complexes, namely, {[Co4(L)2(HCOO)2(OH)2][SiO4(W3O9)4]}·6DMF·5H2O (1) and {[Zn4(L)2(HCOO)2(OH)2][SiO4(W3O9)4]}·6DMF·5H2O (2), have been solvothermally prepared by using a new methyl imidazole functionalized resorcin[4]arene (L), polyoxometalate (POM), and metal cation. Isostructural 1 and 2 feature porous supramolecular architectures and represent an unusual example of a successful combination of resorcin[4]arenes with polyoxometalates. Remarkably, selective adsorptions for organic dyes were studied by using 1 and 2 as adsorbents. Moreover, their electrocatalytic activities for the oxidation of ascorbic acid and reduction of NaBrO3 were also studied.
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