Abstract
This work reports the degenerate two-photon absorption spectrum for a series of Salen complexes possessing two azo dye units. The observed spectra peak at 1000 nm, twice the wavelength of the linear absorption peak, and increase monotonically to the blue due to resonant enhancement of the non linearity. The two-photon absorption properties of these molecules were found to be an additive effect of chromophores and independent of the metal ions. The two-photon absorption spectra were described with a sum-over-states model, from which the transition dipole moment and dipole moment change were determined and compared with quantum chemistry calculation.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
