Abstract
In this work we address the peculiarities of the macroscopic responses in ternary 0.1Na0·5Bi0·5TiO3-0.6SrTiO3-0.3PbTiO3 (0.1NBT-0.6ST-0.3PT) solid solutions. These solid solutions exhibit a spontaneous first order relaxor to normal ferroelectric phase transition. The phase transition is accompanied by a broad dielectric relaxation which expands over 10 orders of magnitude in frequency just above the phase transition temperature. The temperature dependence of polarization shows that non-zero net polarization persists above the phase transition temperature. Below the phase transition temperature, it is not possible to describe the temperature dependence of polarization with a power law function which is valid in normal ferroelectrics. The piezoresponse force microscopy studies reveal that 0.1NBT-0.6ST-0.3PT solids solutions display several local polarization patterns which arise due to the bimodal distribution of grains in the ceramics. We associate the peculiar macroscopic responses to these complex polar structures and their different temperature behaviours.
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